Gather all ingredients and preheat the oven to 350°F (175°C). Lightly coat a baking sheet with cooking spray and set aside.
Place a cast iron skillet over high heat. Allow it to heat for approximately 3–5 minutes, until smoking hot. Make sure the kitchen is well ventilated.
While the skillet heats, combine the paprika, cayenne pepper, ground cumin, dried thyme, onion powder, ground white pepper, and salt in a small bowl. Stir until the spices are evenly mixed.
Lightly spray both sides of the chicken breasts with cooking spray. Sprinkle the spice mixture evenly over the chicken, coating both sides.
Carefully place the seasoned chicken breasts into the hot cast iron skillet. Sear for approximately 1 minute without moving them, allowing a dark, flavorful crust to develop.
Turn the chicken breasts and sear the opposite side for another minute.
Transfer the seared chicken to the prepared baking sheet.
Place the baking sheet in the preheated oven and bake for approximately 5–10 minutes, or until the chicken is fully cooked. An instant-read thermometer inserted into the thickest part should register at least 165°F (74°C). Thicker chicken breasts may require additional baking time.
Remove the chicken from the oven and serve hot with your preferred side dishes.